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December 1, 1985Phosphorous and Sulfur and the Related Elements

Structures of Phosphaethylenes and a 1-Phosphaallene Containing Phosphorus in Lower Coordination State

Masaaki Yoshifuji Kozo Toyota Naoki Inamoto Ken Hirotsu Taiichi Higuchi Shigeru Nagase

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Abstract

The X-ray analyses of sterically protected Z-2-t-butyldimethylsilyloxy-2-phenylphosphaethylene (Z-2) and 3,3-diphenyl-1-phosphaallene (3) were carried out and the structures of the parent compounds, HP[dbnd]CH2 and HP[dbnd]C[dbnd]CH2, were optimized by ab initio methods.

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Yoshifuji et al. (1985) studied this question.

synapsesocial.com/papers/6ab0bab6b955ad5d8b16b43b https://doi.org/10.1080/03086648508072740

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Isolation and characterisation of the first stable diphospha-allene: P,P′-bis(2,4,6-tri-t-butylphenyl)-1,3-diphospha-alleneOriginal Research · 1984 · 73 citations
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3A Very Crowded Molecule: X‐Ray Crystallographic Analysis of Bis(2,4,6‐tri‐tert‐butylphenyl)phosphinic ChlorideOriginal Research · 1980 · 32 citations
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The Nature of the Homonuclear Bond in Organic and Inorganic DichalcogenidesPhosphorous and Sulfur and the Related Elements · 1988
Sulfenamides and Sulfinamides Iv. Homolysis of Sulfenamides in CyclohexenePhosphorous and Sulfur and the Related Elements · 1988
On the Anions of Diphenyl 1-(4-Nitrophenylamino)-1-Arylmethane Phosphonates1Phosphorous and Sulfur and the Related Elements · 1988
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STUDY OF THE ALKALINE CLEAVAGE OF THE P[sbnd]C BOND IN PHOSPHINE OXIDES AND DERIVATIVES OF TRICHLOROMETHANEPHOSPHONATEPhosphorous and Sulfur and the Related Elements · 1988

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