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Either C−H activation or C−C coupling is observed in reactions of titanocene with azines (R 1 R 2 C N−N CR 1 R 2 ), which lead to the formation of complexes 2 and 3, respectively. The reaction with two different metallocene units can yield heterobimetallic bis(alkylideneamido) complexes ( 4 ).
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Ohff et al. (1998) studied this question.
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