A thermoregulated catalytic process has been elaborated using a ruthenium‐nanoparticle catalyst embedded into a supramolecular cyclodextrin‐based hydrogel matrix. Upon heating, the gel phase turned into a sol phase in which alkenes could be efficiently hydrogenated. Upon cooling, the reaction products and the metallic catalyst could be easily separated. The reusability of the system was clearly demonstrated.
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Léger et al. (2012) studied this question.
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