Hydrophilic/Hydrophobic Interphase-Mediated Bubble-like Stretchable Janus Ultrathin Films toward Self-Adaptive and Pneumatic Multifunctional Electronics

As promising candidates for intelligent biomimetic applications similar to living organisms, smart soft materials have aroused extensive interest due to their extraordinarily designable structures and functionality. Herein, a bubble-like elastomer-based electronic skin that can be pneumatically actuated is achieved through hydrophilic/hydrophobic interphase mediated asymmetric functionalization. The asymmetric and controllable introduction of elastic polydimethylsiloxane into the carbon nanotube film at the air/water interface can endow the Janus ultrathin film with tunable conductivity, self-adhesivity, self-adaptivity, and even self-sealing properties. As a result, the Janus films can be employed as multifunctional electronics, including self-adhesive strain sensing/thermal managing devices and even noncontact mechanical sensors as artificial eardrums for tiny air-pressure detection. Significantly, these excellent features can further enable the integration of actuating and sensing functions. As a proof of concept, the Janus film can serve as a self-supported device to simultaneously imitate the controllable contracting/expanding behaviors of the vocal sac of frog and monitor the real-time current change in this process, demonstrating significant potential in smart bionic applications.