A new protocol for the coupling of aryl iodides with thiophenols and alkanethiols catalyzed by copper nanoparticles under ligand‐free condition has been developed. A variety of functionalized aryl sulfides are prepared in excellent yields under microwave irradiation for 5–7 min. A plausible radical mechanism has been suggested.
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Ranu et al. (2007) studied this question.
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