Trading places: Bifunctional thiol ligands were immobilized onto positively charged silica gel and onto Rink resin through electrostatic interactions. The image shows the place-exchange reaction between the alkanethiolate-protected gold nanoparticles and the polymer-bound bifunctional thiol ligands; monocarboxyl gold nanoparticles were obtained as the major product, cleaved off from the polymer support under mild conditions.
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Liu et al. (2006) studied this question.
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