A new equation for salt effect in vapor‐liquid equilibrium is presented, which correlates temperature and the liquid‐phase concentrations of all three components with equilibrium vapor composition, for isobaric systems consisting of a binary to which • salt has been added to saturation. The equation, of form was tested successfully with literature data for 12 ethanol‐water‐salt systems, yielding a better fit for all 12 systems than the one‐constant equation of Johnson and Furter, and with the confidence level for the comparison in excess of 99.9% for six of thesystems tested.
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Jaques et al. (1972) studied this question.
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