A β-diketiminate complex of indium, [In{N(2,4,6-Me3C6H2)C(Me)}2CH], dimerizes in the solid state (see space-filling model) to provide an indium species that is formally isoelectronic to the historically significant bis(stannane)diyls. A direct InIn bond is formed yielding a centrosymmetric dimer that possesses approximate C2h symmetry with a mutual trans-bent orientation of the N-chelating ligands.
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Hill et al. (2005) studied this question.
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