Pentacoordinate planar nonmetals (PPNs) centered in perfect pentagonal hydrocopper complexes Cu5H5X (X = B, C, N, O), as determined by density functional theory methods, are presented in this communication. The results obtained in this work complete the hypercoordinate planar carbon series with high symmetries (D4h, D5h, and D6h), and may shed new insight in catalyst chemistry. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)
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Li et al. (2004) studied this question.
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