⌘+K

Pulse Explore Communities Researchers Journals

Home Communities Explore

February 23, 2000Inorganic Chemistry

Solid State Structures of [Ag5(dppm)4(S2CC(CN)P(O)(OEt)2)2][PF6] and Ag4(dppm)4(S2CC(CN)P(O)(OEt)2)2: Variable Coordination Modes of 1,1-Dithiolate to Silver(I)

C. W. Liu Ben‐Jie Liaw Ju-Chung Wang Tai‐Chiun Keng

View at Publisher

Ask AI

Bookmark

Share

Abstract

A novel pentanuclear silver complex [Ag5(dppm)4(S2CC(CN)P(O)(OEt)2)2][PF6], containing bridging dppm and 2-(diethoxyphosphinyl)-2-cyanoethylene-1,1-dithiolato ligands of which the 1,1-dithiolates exhibit an unprecedented tetrametallic hexaconnective coordination pattern, is reported.

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Liu et al. (2000) studied this question.

synapsesocial.com/papers/6ab23966a298b2851407db82 https://doi.org/10.1021/ic991012s

View at Publisher

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1The Mechanism of Zinc(II)-Dithiocarbamate-Accelerated Vulcanization Uncovered; Theoretical and Experimental EvidenceOriginal Research · 1998 · 188 citations
2Zinc(II)‐Catalyzed Disproportionation in Rubber: The mechanism of Sulfur Vulcanization RevisitedOriginal Research · 1997 · 29 citations
3Novel dithio- and diseleno-carbamates of zinc and cadmium as single-molecule precursors for low-pressure metal-organic chemical vapour depositionOriginal Research · 1996 · 63 citations
4A new metal cluster system containing a cube of metal atomsOriginal Research · 1968 · 101 citations
5Crystallographic evidence for copper-copper bonding at 2.8 Ang. Crystal and molecular structure of tetrakis(tetraphenylphosphonium) hexakis(1,2-dithiosquarato)octacuprate(I)Original Research · 1974 · 51 citations

Synthesis and Characterization of Luminescent Square-Planar Platinum(II) Complexes Containing Dithiolate or Dithiocarbamate Ligands1994
Tuning the Excited-State Properties of Platinum(II) Diimine Dithiolate Complexes1996
Synthesis and Structural Characterization of Neutral Silver(I) Complexes with Arenephosphinothiols. Crystal Structures of [Ag<sub>4</sub>{2-(Ph<sub>2</sub>P)-6-(Me<sub>3</sub>Si)C<sub>6</sub>H<sub>6</sub>S}<sub>4</sub>] and [Ag<sub>4</sub>{2-(Ph<sub>2</sub>PO)-6-(Me<sub>3</sub>Si)C<sub>6</sub>H<sub>3</sub>S}<sub>4</sub>]1999
Enhanced Antithermal Quenching of Hybrid Pb(II)- and Bi(III)-Based Metal Halides for Phosphor-Converted Light-Emitting DiodesInorganic Chemistry · 2026
Chemical Origins of Line Broadening in the f–f Transitions of a Molecular Yb(III) ComplexInorganic Chemistry · 2026

More from Inorganic Chemistry