Asymmetric zinc porphyrin (ZnPy) was synthesized and used to sensitize nanosized TiO2. The visible-light-driven activity of CO2 photoreduction to generate CO/CH4 in the gas phase was observed from the ZnPy-sensitized TiO2 without loading noble metal, and the mechanism was discussed.
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Li et al. (2015) studied this question.
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