We have studied the first-order magnetic phase transition and related physical properties of MnFeP0.5As0.4Si0.1 by means of x-ray diffraction, magnetization, thermal expansion, and electrical resistance measurements. The compound crystallizes in the hexagonal structure with Fe2P-type. The temperature dependence of magnetization shows a first-order magnetic phase transition around 299 K. There is no crystallographic structural transition associated with the magnetic phase transition. The linear thermal expansion shows that this magnetic phase transition is accompanied by a negative volume change. The electrical resistance shows an anomalous behavior at the transition, which is probably caused by the change in c/a ratio.
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Tegus et al. (2003) studied this question.