Rock/water interaction in dielectric properties; experiments with hydrophobic sandstones

The dielectric constant of a partially saturated sandstone varies as a function of the level of water saturation. Experimental data indicate that rock/water interaction, at low saturations, has a large effect on the measured dielectric response. To theoretically predict the dielectric constant of the rock/water/air system, this rock/water interaction must be accounted for by including the effect of the water wetting the rock solid. Alternatively, if the rock/water interaction can be eliminated, a three-component (dry rock, water, and air) mixing law can be used to model the dielectric behavior. In this laboratory study, a chemical treatment is used to change four water-wet sandstones into hydrophobic sandstones. In three hydrophobic samples the rock/water interaction, seen in the data for the water-wet samples, is eliminated and the dielectric constant of the partially saturated sandstones can be simply modeled as a dry rock/water/air system. This experimental study illustrates the importance of the chemical state of the rock surfaces in determining the dielectric behavior of sandstones.