Coordination-bond-directed synthesis of hydrogen-bonded organic frameworks from metal–organic frameworks as templates

center are critical to breaking the Cu-carboxylate bonds, while the synergic corbelled S⋯S and π⋯π interactions in the framework ensured stability of materials during post-synthetic modification. This work not only provided a strategy to guide the design and discovery of new HOFs, but also linked the research of MOFs and HOFs.