A supercritical fluid nuclear magnetic resonance (scNMR) spectroscopic method has been developed using a commercially available NMR spectrometer equipped with a high-pressure zirconia cell, revealing that trialkylphosphite ligands are highly effective for increasing the solubility of dichloropalladium(II) and dichlororuthenium(II) complexes in supercritical carbon dioxide (scCO2).
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Kayaki et al. (2002) studied this question.
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