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January 1, 2003Journal of Coordination Chemistry

Synthesis and Characterization of New Azopyrimidine Complexes

Amina A. Soayed Osama K. Sharsherh Alaa E. Ali

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Abstract

New azo compounds containing barbituric acid, thiobarbituric acid or thiouracil, together with their complexes, were prepared.All the complexes are tetrahedral.Axial ESR spectra were observed for the complexes with a d x2Ày2 ground state with small g || values indicating strong interaction between the ligands and their metal ions.Conductivity measurements proved semiconducting properties for the ligands and their complexes.Energies of activation (ÁE a ) and order of the thermal reactions (n) were calculated by DTA.

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Soayed et al. (2003) studied this question.

synapsesocial.com/papers/6ab376d6f522bae22b32b59b https://doi.org/10.1080/0095897031000115920

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