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September 12, 2001Inorganic Chemistry

Characterization and Bonding of the Cation [Ge{N(C6H3-2,6-i-Pr2)CMe}2CH]+: Comparison with the Isoelectronic Ga{N(C6H3-2,6-i-Pr2)CMe}2CH

Matthias Stender A.D. Phillips Philip P. Power

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Abstract

Reaction of Ge(Cl)Dipp2nacnac (Dipp2nacnac = {N(C6H3-2,6-i-Pr2)C(Me)}2CH) with B(C6F5)3 in the presence of H2O affords the salt [Ge(Dipp2nacnac)][HO{B(C6F5)3}2] whose cation [Ge(Dipp2nacnac)]+ is isoelectronic to its neutral gallium analogue Ga(Dipp2nacnac).

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Cite This Study

Stender et al. (2001) studied this question.

synapsesocial.com/papers/6ab380df2e51be655ef55a6c https://doi.org/10.1021/ic0155582

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