Recently a new theoretical method of a quantitative analysis of surface energetic heterogeneity from the experimental TPD spectra, based on the statistical rate theory of interfacial transport has been proposed by Rudzinski and co-workers. The purpose of the present publication is to show the predictive features of that new method. Also prospects of a further generalization of that method toward taking into account readsorption effects are discussed.
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Rudziński et al. (1997) studied this question.
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