The zirconium phosphinidene complexes [Cp2Zr=PDmp(PR3)] (Dmp = 2,6-Mes2C6H3; R = Me: 1a; R = Bu: 1b) form the diphosphene DmpP=PDmp, [Cp2ZrCl2], and the phosphoranylidenephosphines DmpP=PR3 (3a, 3b) upon reaction with DmpPCl2.
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Urnéžius et al. (1999) studied this question.
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