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The trans-geometrical isomer of the first Pt(IV) complex with the tetradentate ligand 1,3-propylenediamine-N,N′-diacetate ion (pdda) was prepared by a direct synthesis from potassium hexachloroplatinate(IV) and pdda in the presence of lithium hydroxide. The crystal structure of trans-[Pt(pdda)Cl2]·H2O complex has been determined. The Pt(IV) ion has a distorted octahedral coordination due to intramolecular N–H···Cl interactions.
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Ðinović et al. (2004) studied this question.
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