Anatomy of a P3− synthon: The Ph3SnP3(C6H8) molecule (see picture; Sn red, P orange) has been synthesized by triphosphorus transfer from a niobium complex. This molecule was shown to be a viable source of P3− in a proof-of-principle reaction: loss of Ph3SnCl and 1,3-cyclohexadiene from Ph3SnP3(C6H8) upon treatment with Wilkinson's catalyst, [ClRh(PPh3)3], gives rise to the new cyclo-P3 complex [(η3-P3)Rh(PPh3)3].
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Cossairt et al. (2010) studied this question.
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