A theoretical study on the phase stability of III–V pseudobinary semiconductor alloys is conducted by combining the pseudopotential calculation with the Cluster Variation Method. Thermal vibration effects are also incorporated based on the Debye-Gruneisen model. Calculated thermodynamic properties including a phase diagram for GaAs-InAs system are demonstrated. A possibility of the appearance of ordered compounds for a thin film is discussed.
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Tetsuo Mohri (1994) studied this question.
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