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Heptacoordinated nickel(II) complexes characterized by substantial Ising-type single-ion anisotropy have been involved in the construction of two pentanuclear [Ni3W2] compounds by association with [W(CN)8](3-). For one of them, slow relaxation of magnetization was observed to occur concomitantly with antiferromagnetic ordering.
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Gogoi et al. (2013) studied this question.
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