A Re–Pd heterometallic core has been constructed inside the cavity of a calixarene ligand. An unprecedented calix[4]arene–rhenium complex can incorporate a {Pd(η3-C3H5)+} fragment to afford the phenoxo-bridged heterodinuclear complex [ReO2{p-tBu-calix[4]arene-(O)4}Pd(η3-C3H5)] (see picture).
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Iwasa et al. (2003) studied this question.
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