Local structure at the manganese site in mixed-valence manganites

Extended x-ray absorption fine structure at the manganese K edge has been used to study the first oxygen coordination shell at the manganese site as a function of temperature in mixed-valence perovskites. La_1-xCaₓMnO₃ ($x=0,$ 0.15, 0.33, 0.5, 0.66, and 1), La0.60Y0.07Ca1/3MnO₃, La0.57Tb0.1Ca1/3MnO₃, and Tb_1-xCaₓMnO₃ ($x=0,$ 0.33, 0.5, and 0.67) were studied. Our results show that the manganese atom is surrounded by a regular oxygen octahedra in the metallic-ferromagnetic phase. The analysis of the spectra at temperatures above the magnetic transition can be described in terms of either a unique Mn-O interatomic distance with a large Debye-Waller factor or two Mn-O distances with a distortion lower than 0.1 {}. Such distortion or disorder must be dynamic since it cannot be detected by diffraction measurements. This result supports the evidence of a large phonon-electronic interaction and the polaronic origin as a possible mechanism of electrical conduction in the paramagnetic phase.