A nonperturbative expression for the rate of dissociation from the ground vibrational state of a diatomic molecule in the presence of an infrared laser field is derived using R-matrix techniques. No rotating wave approximation and no metastable levels are introduced. The result is applied to a model system and to HF to obtain the dependence of multiphoton dissociation rate upon laser frequency and intensity. Dissociation is predicted at fields of order 1013 W/cm2.
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Whaley et al. (1982) studied this question.
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