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The title compound 1 consisting of two N,N,N′,N′‐tetramethyl‐p‐phenylenediamine (TMPD) units in a [3.3]paracyclophane system has been synthesized starting from 2 via 3–10 and 13. The molecular structure of 1 is discussed on the basis of an X‐ray structure analysis. Electron‐donor properties of 1 are reported.
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Staab et al. (1987) studied this question.
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