January 1, 1970Journal of the Chemical Society D Chemical Communications

A novel route to D-homoandrostane derivatives, including new methods for the preparation and reduction of hydroxy-azides

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Abstract

The sequence: oxiran (VI)→ hydroxy-azide (VII)→ hydroxy-amine (III)→ ketone, using novel reaction conditions, provides a convenient general route for the preparation of D-homo-steroids.

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Cite This Study

KIRK et al. (1970) studied this question.

synapsesocial.com/papers/6ab5cc4d645c39a44f7c687a https://doi.org/10.1039/c2970000064b

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Abstract

The sequence: oxiran (VI)→ hydroxy-azide (VII)→ hydroxy-amine (III)→ ketone, using novel reaction conditions, provides a convenient general route for the preparation of D-homo-steroids.