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We investigated the effect of starting powder on the microstructure and superconducting properties of MgB 2 tapes prepared by a powder-in-tube technique. Two kinds of powder mixtures, Mg + B and MgH 2 + B, were used as precursors. When using the mixture of Mg + B, carbon-steel (CS) sheaths reacted with B, and Fe x B ( x = 1 and 2) was formed. This brought about a decrease in the density of the MgB 2 core and, hence, a low critical current density ( J c ). On the other hand, we found that the mixture of MgH 2 + B was effective in suppressing the formation of Fe x B and obtaining a high density of the core layer. The J c values of the tapes prepared using the mixture of MgH 2 + B were about twice as large as those prepared using the mixture of Mg + B and reached 1600 A cm −2 at 4.2 K and 10 T. This is higher than that of the CS-sheathed MgB 2 tapes prepared with MgB 2 powder.
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Fujii et al. (2002) studied this question.
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