Valencies get remix: A unique kind of electronic structure (Mn+0.5)(μ-L.−)(Mn+0.5) which was previously discussed only for metal–ligand charge-transfer (MLCT) excited states is established structurally and by quantum chemical analysis for both rac (see picture) and meso isomers of [(μ-abpy){Ru(acac)2}2] (abpy=2,2′-azobispyridine, acac−=acetylacetonate).
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Sarkar et al. (2005) studied this question.
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