First-principle theory calculations reveal record coordination numbers of CN = 13 in D 13h La©C 13 + , CN = 12 in C 2v Y©B 6 C 6 + , and CN = 11 in C 2v Sc©B 5 C 6 in planar species, effectively enriching the chemical structures and bonding patterns of planar hypercoordinated complexes.
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Lu et al. (2021) studied this question.
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