Chemical recognition based on micromachined silicon cantilever array

We report on the performance of a measurement system for the recognition of individual analytes and their binary mixtures which is based on a multiarray of four micromachined silicon cantivelers actuated at their resonance frequency. The cantilevers have been functionalized by organic polymers [polydimethylsiloxane (PDMS) and polyvinylpyridine (PVP)] and amorphous nitrogen-rich carbon nitride films. We found that the sensitivity and selectivity of the cantilevers coated with CNx films change according to the layer thickness. Our results show that the selected combination of sensitive layers ensures a wide range of specific, reversible and reproducible sensor responses upon exposure to methanol, 2-propanol, water and their binary mixtures. Further, it was found that the differences in recovery times of PDMS and CNx films after exposure to the two alcohols and their mixtures could be used especially for low analyte concentrations as a second characteristic in addition to the resonance frequency shift for the identification of individual components in the mixtures.