This paper proposes the detection of the variation in the proton-to-electron mass ratio β by measuring a pure vibrational transition frequency of a cold CaH + ion. The uncertainty of the this frequency can potentially be on the order of 10 −16 , because the uncertainties of the Zeeman and Stark shifts are lower than 10 −16 and the electric quadrupole shift is zero. It is practicable to produce a CaH + ion at a certain quantum state and perform sympathetic cooling by using the collisions with a laser-cooled Ca + ion.
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Kajita et al. (2009) studied this question.
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