Magnesium amidoborane monoammoniate (Mg(NH(2)BH(3))(2) x NH(3)) which crystallizes in a monoclinic structure (space group P2(1)/a) has been synthesized by reacting MgNH with NH(3)BH(3). Dihydrogen bonds are established between coordinated NH(3) and BH(3) of [NH(2)BH(3)](-) in the structure, promoting stoichiometric conversion of NH(3) to H(2).
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Chua et al. (2010) studied this question.
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