More rapidly to the target: Screening experiments in a miniautoclave demonstrate the different effects of catalytically active additives such as Raney nickel and basic alkali-metal compounds on the reaction of methane in supercritical water. Accordingly, this opens up the possibility to convert methane into hydrogen and carbon dioxide with water in a single process step without the need to pass through the intermediate carbon monoxide stage which is currently necessary in industrial set ups (see scheme).
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Kruse et al. (2003) studied this question.
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