Sulfonate Retention by Kaolinite at High pH—Effect of Inorganic Anions

Summary At high pH and with surfactant concentrations well above the critical micelle concentration (CMC), the pH-dependent part of adsorption is small. Retention depends especially on the sodium-ion activity and on the type and valence of inorganic anions. As the anionic charge increases, adsorption at a given ionic strength decreases. This behavior correlates with the effect of anions on the sulfonate activity in solution.