The shape of photoionization spectrum connected with removal of an electron from the 3dn shell of a transition metal impurity into the conduction band has been calculated. The influence of configurational mixing between 4pn and 3dn states on the shape of the spectrum is discussed. The absorption coefficient for uniaxial crystals (α for E ‖ c and E ⊥ c, c crystal axis) is given.
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Jerzy M. Langer (1971) studied this question.
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