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A Monte Carlo model is derived and combined with an existing detector response function model to ptdict the entire pulse‐height spectra for energy‐dispersive, x‐ray fluorescence systems that consist of an annular‐ring, photon exciting source, a coaxially positioned right circular homogental sample, and a cirular si(Li) detector. A method is dervied and demonstrated for using the predicted and experimental pulse‐height spectra on a chi‐square basis to determine elemental amounts. This approach allows the use of all the information available in an entire energy‐dispersive, x‐ray fluorescence pulse‐hight spectrum for analysis purposes.
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Doster et al. (1982) studied this question.
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