The asymmetric epoxidation of unfunctionalised olefins to epoxides is realised by using manganese(III) complexes stabilised on nanocrystalline magnesium oxide in the presence (1R,2R)‐(−)‐diaminocyclohexane as a chiral ligand in good yields and up to 91 % enantiomeric excess.
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Choudary et al. (2006) studied this question.
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