Don't play the second fiddle! The identification of different arrangements of branched-chain keto acid dehydrogenases usually involved in the biosynthesis of cellular building blocks is demonstrated (see scheme). Direct cross talk between secondary metabolism ketosynthases (KS) and fatty acid biosynthesis is shown and the biosynthesis of odd-numbered iso-fatty acids is found to be connected to the production of pristinamycin IIa.
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Brachmann et al. (2012) studied this question.
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