We present Maxwellian-averaged effective collision strengths for the electron-impact excitation of S iii over a wide range of electron temperatures of astrophysical importance, log T e (K) = 3.0–6.0. The calculation incorporates 53 fine-structure levels arising from the six configurations—3 s 2 3 p 2 , 3 s 3 p 3 , 3 s 2 3 p 3d, 3 s 2 3 p 4 s , 3 s 2 3 p 4 p , and 3 s 2 3 p 4 d —giving rise to 1378 individual lines and is undertaken using the recently developed RMATRX II plus FINE95 suite of codes. A detailed comparison is made with a previous R -matrix calculation and significant differences are found for some transitions. The atomic data are subsequently incorporated into the modeling code cloudy to generate line intensities for a range of plasma parameters, with emphasis on allowed ultraviolet extreme-ultraviolet emission lines detected from the Io plasma torus. Electron density-sensitive line ratios are calculated with the present atomic data and compared with those from CHIANTI v7.1, as well as with Io plasma torus spectra obtained by Far-Ultraviolet Spectroscopic Explorer and Extreme-Ultraviolet Explorer . The present line intensities are found to agree well with the observational results and provide a noticeable improvement on the values predicted by CHIANTI.
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