Abstract (R)-, (S)-, and (RS)-1-phenylethylcarbamates of cellulose and amylose were synthesized and used as chiral stationary phases for high-performance liquid chromatography. The chiral recognition abilities of the 1-phenylethyl derivatives depended greatly on the chirality of 1-phenylethyl groups. Among six derivatives, amylose tris((S)-1-phenylethylcarbamate) showed high optical resolving ability for many compounds.
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Okamoto et al. (1990) studied this question.
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