An ultraviolet photoelectron spectrum of phenyl α-nitronyl nitroxide (PNN) has been studied in the gas phase, in order to understand the potentiality of the α-nitronyl nitroxide radical family yielding ferromagnetic intermolecular coupling. The observed spectrum has been well interpreted with the help of CNDO-CI calculation. Very strong spin polarization effect has been suggested, which is advantageous for the intermolecular ferromagnetic coupling.
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Waga et al. (1993) studied this question.
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