Adiabatic electron affinity (aEA) of SF6 was calculated on the SCF level using large basis sets on both sulfur and fluorine. The calculated value of aEA was 0.3 eV. d-type polarization function on fluorine was shown to affect the value of aEA more than the 3d orbital on sulfur. Inclusion of f-type function on sulfur was discussed.
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Kłobukowski et al. (1987) studied this question.
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