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An enantiotropic transition between crystal and amorphous phases of a thermotropic liquid crystalline polyester, poly(4,4′-dioxy-2,2′-dimethylazoxybenzene dodecanedioyl) (labeled as DDA-9), was found to be induced at room temperature by hydrostatic pressure. The pressure-induced enantiotropic transition is greatly de-pendent upon the original solid state of DDA-9.
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Maeda et al. (1986) studied this question.
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