Hetero Diels–Alder reactions of 3,5-di-tert-butyl-o-benzoquinone with acyclic dienes: novel synthesis of 1,4-benzodioxines

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Abstract

3,5-Di-tert-butyl-o-benzoquinone acts as a 1,4-dioxabutadiene in its reaction with acyclic dienes leading to 1,4-benzodioxines in very high yields.

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Nair et al. (1994) studied this question.

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3,5-Di-tert-butyl-o-benzoquinone acts as a 1,4-dioxabutadiene in its reaction with acyclic dienes leading to 1,4-benzodioxines in very high yields.