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The influence of pH on the kinetics of ozone decomposition in water was studied. Over the pH range 1–8, the kinetics was well described by a second-order reaction equation. Starting with approximately pH 3, the pH dependence of the logarithm of the constant at 19°C corresponded to the equation log k = −2.66 + (0.49 ± 0.03)pH. The activation energy of ozone decomposition was found to be 76.0 ± 8.3 kJ/mol.
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Ершов et al. (2009) studied this question.
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