A novel metallopolymer of DM-DCNQI (2,5-DM-DCNQI = 2,5-dimethyl-N,N‘-dicyanoquinone diimine) has been structurally determined. [Mo2(O2CCF3)4(2,5-DM-DCNQI)·C6H6]n crystallizes with enclathrated benzene which forms π-stacks with DM-DCNQI along the c direction. The orientation of the zigzag chains viewed down the c axis involves an ...ABAB... pattern wherein the Mo2 units in adjacent chains are oriented perpendicular to each other as depicted in the diagram below.
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Ouyang et al. (1996) studied this question.
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