Thermolysis of overcrowded 2,3-diphenylgermirenes bearing bulky substituents on the germanium atom in benzene affords the corresponding kinetically stabilized germylenes, the efficient formation of which is evidenced by the trapping experiments with 2,3-dimethyl-1,3-butadiene. This provides a new and mild method for the generation of germylenes.
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Tokitoh et al. (1995) studied this question.
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