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Fluorous nanophase in the pore: Perfluoroalkyl chain-anchored bridging ligands are assembled, upon complexation with Co(NCS)2, into coordination networks with fluorous pores that show fluorophilic/organophobic properties. The perfluoroalkyl chains are considerably disordered and seem to tumble in the pores, forming a nanoscopic pseudo liquid phase in the solid.
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Jang et al. (2009) studied this question.
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